There is a quantum mechanical condition that in order for a molecular vibration to be observed in the IR there must be a dipole moment change accompanying the vibration. It is called a selection rule (google). For homonuclear diatomic molecules, A2, the stretch, ↔A-A↔ , is silent in the IR because the molecule does not have a dipole. H2, N2, O2, F2 (etc) fit into this category. For heteronuclear AB diatomics there is necessarily a dipole and hence a change with the ν(A-B): ↔δ+A-Bδ-↔. These molecules will have a stretching absorption in the IR.
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2017-03-01 10:00:58 UTC
Nitrogen Ir Peaks
StrobeLight Nick
2010-05-31 06:58:42 UTC
I guess Nitrogen just absorbs IR light and re-emmits it as another light.
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